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µÚ1Õ ˫½ðÊôЭͬ´ß»¯¸ÅÊö 001
1.1 Ë«½ðÊôЭͬ´ß»¯»ù´¡ 002
1.2 µäÐ͵ÄË«½ðÊôЭͬ´ß»¯»úÀí 005
1.2.1 Pt-RuË«½ðÊôЭͬ´ß»¯¼×´¼Ñõ»¯·´Ó¦»úÀí 005
1.2.2 Ni-FeË«½ðÊôÎöÑõ·´Ó¦»úÀí 012
1.3 ½áÓï 018
²Î¿¼ÎÄÏ× 019

µÚ2Õ ˫½ðÊôЭͬ´ß»¯ÌåϵÔÚȼÁϵç³ØºÍÇâÄÜÖеÄÓ¦Óà 023
2.1 Ö±½Ó¼×´¼È¼Áϵç³ØÑô¼«Ñõ»¯·´Ó¦ 025
2.2 Ö±½ÓÒÒ´¼È¼Áϵç³ØÑô¼«Ñõ»¯·´Ó¦ 030
2.3 Ö±½Ó¼×ËáȼÁϵç³ØÑô¼«Ñõ»¯·´Ó¦ 034
2.3.1 Pt»ùË«½ðÊô´ß»¯¼ÁÓÃÓÚ¼×ËáÑõ»¯ 035
2.3.2 Pd»ùË«½ðÊô´ß»¯¼ÁÓÃÓÚ¼×ËáÑõ»¯ 039
2.4 ÑõÆøÎö³ö·´Ó¦ 043
2.4.1 Fe-Co»ùË«½ðÊô´ß»¯¼Á 044
2.4.2 Ni-Co»ùË«½ðÊô´ß»¯¼Á 046
2.4.3 Ni-AlºÍNi-CrË«½ðÊô»ù´ß»¯¼Á 047
2.4.4 Cu²ôÔÓµÄNi¡¢Fe¡¢CoË«½ðÊô»ù´ß»¯¼Á 048
2.4.5 ÆäËûË«½ðÊô»ù´ß»¯¼Á 049
2.5 ȼÁϵç³ØÒõ¼«ÑõÆø»¹Ô­·´Ó¦ 051
2.5.1 Ë«½ðÊôPt-NiºÏ½ð´ß»¯¼Á 053
2.5.2 ÆäËûË«½ðÊôPt-MºÏ½ð´ß»¯¼Á 056
²Î¿¼ÎÄÏ× 058

µÚ3Õ ¸ßÐÔÄÜPt»ùË«½ðÊô´ß»¯¼ÁÓÃÓÚ¼×´¼Ñõ»¯ 067
3.1 Pt-OsË«½ðÊôЭͬ´ß»¯¼Á 068
3.1.1 ¸ß·Öɢ˫½ðÊôPt-OsÄÉÃ×´ß»¯¼ÁµÄÖƱ¸ 070
3.1.2 ¸ß·Öɢ˫½ðÊôPt-OsÄÉÃ×´ß»¯¼ÁµÄ±íÕ÷ÓëÆÀ¼Û 071
3.1.3 Á½ÖÖ²»Í¬·½·¨ÖƱ¸µÄPt-Os´ß»¯¼ÁµÄ´ß»¯ÐÔÄÜ 072
3.2 Ë«½ðÊôPt-RuºË¿Ç½á¹¹´ß»¯¼Á 082
3.2.1 ºË¿Ç½á¹¹Pt/TiO2@Ru-C´ß»¯¼ÁµÄÖƱ¸ 084
3.2.2 ºË¿Ç½á¹¹Pt/TiO2@Ru-C´ß»¯¼ÁµÄ±íÕ÷ÓëÆÀ¼Û 085
3.2.3 ºË¿Ç½á¹¹Pt/TiO2@Ru-C´ß»¯¼ÁµÄ´ß»¯ÐÔÄÜ 085
3.3 Ë«½ðÊôPt-Os´ß»¯¼ÁÓëPt-Ru£¨TiO2Îȶ¨µÄ£©´ß»¯¼ÁÐÔÄÜ±È½Ï 095
²Î¿¼ÎÄÏ× 096

µÚ4Õ Pt-PdË«½ðÊôЭͬ´ß»¯ÓÃÓÚ¼×ËáµçÑõ»¯ 103
4.1 ¸ß·ÖÉ¢Pd-PtË«½ðÊô´ß»¯¼Á 105
4.1.1 ¸ß·ÖÉ¢Pd-PtË«½ðÊô´ß»¯¼ÁµÄÖƱ¸ 106
4.1.2 ¸ß·ÖÉ¢Pd-PtË«½ðÊô´ß»¯¼ÁµÄ±íÕ÷ÓëÆÀ¼Û 107
4.1.3 ¸ß·ÖÉ¢Pd-PtË«½ðÊô´ß»¯¼ÁÐÔÄÜÌÖÂÛ 108
4.2 ¸ßÐÔÄÜÌ¿ÔØ΢Á¿²¬ÐÞÊεÄîÙ´ß»¯¼Á 115
4.2.1 ԭλµçÖû»·¨ÖƱ¸Ì¿ÔØ΢Á¿²¬ÐÞÊεÄîÙ´ß»¯¼Á 117
4.2.2 Ì¿ÔØ΢Á¿²¬ÐÞÊεÄîÙ´ß»¯¼ÁµÄ±íÕ÷¼°ÆÀ¼Û·½·¨ 117
4.2.3 ԭλµçÖû»·¨ÖƱ¸µÄÌ¿ÔØPt1@Pdx/C´ß»¯ÐÔÄÜÌÖÂÛ 118
4.3 ´Ó¸ß·ÖÉ¢Pd-PtË«½ðÊô´ß»¯¼Áµ½Î¢Á¿PtÐÞÊεÄPd´ß»¯¼Á 127
²Î¿¼ÎÄÏ× 128

µÚ5Õ ¸ßЧNi-FeË«½ðÊô´ß»¯¼ÁÓÃÓÚÎöÑõ·´Ó¦ 133
5.1 ÅÝÄ­ÄøÉÏԭλµç³Á»ý»¨°ê×´NiFeOxHy/rGO 134
5.1.1 »¨°ê×´NiFeOxHy/rGOµç¼«µÄÖƱ¸ 135
5.1.2 »¨°ê×´NiFeOxHy/rGOµç¼«µÄ±íÕ÷ÓëÆÀ¼Û 135
5.1.3 »¨°ê×´NiFeOxHy/rGOµç¼«µç´ß»¯OERÐÔÄÜ 136
5.2 Ni-FeºÏ½ðÅÝÄ­ 142
5.2.1 Ni-FeºÏ½ðÅÝÄ­µÄÖƱ¸ 143
5.2.2 Ni-FeºÏ½ðÅÝÄ­µÄ±íÕ÷ÓëÆÀ¼Û 143
5.2.3 Ni-FeºÏ½ðÅÝÄ­µÄµç´ß»¯OERÐÔÄÜ 144
5.3 ´ÓNiFeOxHy/rGO/NFµç¼«µ½Ë«½ðÊôNi-FeÅÝÄ­ºÏ½ðµç¼« 151
²Î¿¼ÎÄÏ× 152

µÚ6Õ ¸ßЧ˫½ðÊôЭͬ´ß»¯ÎöÑõºÍÑõ»¹Ô­·´Ó¦ 157
6.1 Ni-CoË«½ðÊôЭͬ´ß»¯ÎöÑõºÍÑõ»¹Ô­·´Ó¦ 158
6.1.1 ¼¹×µ×´NiCo2O4ÄÉÃײÄÁϵÄÖƱ¸ 158
6.1.2 ¼¹×µ×´NiCo2O4ÄÉÃײÄÁϵıíÕ÷ÓëÆÀ¼Û 159
6.1.3 ¼¹×µ×´NiCo2O4ÄÉÃײÄÁϵĵç´ß»¯OER¼°ORRÐÔÄÜ 160
6.2 Ag-MoË«½ðÊôЭͬ´ß»¯ORR·´Ó¦ 167
6.2.1 Ag-MoË«½ðÊô´ß»¯¼ÁµÄÖƱ¸ 168
6.2.2 Ag-MoË«½ðÊô´ß»¯¼ÁµÄ±íÕ÷ÓëÆÀ¼Û 168
6.2.3 Ag-MoË«½ðÊô´ß»¯¼Áµç´ß»¯ORR·´Ó¦ 169
6.3 Ni-CoË«½ðÊô´ß»¯¼ÁºÍAg-MoË«½ðÊô´ß»¯¼ÁµÄ±È½Ï 172
²Î¿¼ÎÄÏ× 173