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¢ñInorganic Chemistry1 Chapter 1Introduction2 1ª±1Observations and Conclusions3 1ª±2The Scientific Method3 1ª±3Units of Measurement5 1ª±4Advice on Studying Chemistry8 Key Words8 Chapter 2Structures of Atoms9 2ª±1Particles in Atoms10 2ª±2The Bohr Model12 2ª±3The Wave Theory of Electrons13 2ª±4Heisenberg¬ðs Uncertainty Principle14 2ª±5The Schr¢‰dinger Equation14 2ª±6Quantum Numbers15 2ª±7Shapes of Atomic Orbitals17 2ª±8Manyª²Electron Atoms19 2ª±9Valence Electrons24 2ª±10The Periodic Table and Electronic Configurations of Atoms24 2ª±11The Periodicity of the Properties of Elements and Atomic Structure26 Key Words30 Exercises31 Chapter 3Chemical bonds33 3ª±1Ionic Bonds33 3ª±2Covalent Bonds35 3ª±3Lewis Dot Symbols and Lewis Structure37 3ª±4Sigma and Pi Bonds43 3ª±5Bond Polarity44 3ª±6Bond Energy, Bond Length and Bond Angle45 3ª±7Molecular Geometry47 3ª±8The VSEPR Model47 3ª±9Hybrid Orbitals51 3ª±10Molecular Orbitals56 3ª±11Intermolecular Force64 Key Words71 Exercises71 Chapter 4Thermochemistry74 4ª±1First Law of Thermodynamics74 4ª±2Enthalpy and Enthalpy Change75 4ª±3Hess¬ðs Law76 4ª±4Entropy and the Second Law of Thermodynamics 79 4ª±5Spontaneous Processes and Gibbs Free Energy80 4ª±6Temperature and Direction of Spontaneous Change81 4ª±7Standard Free Energy of Formation and Standard Free Energy of Reaction82 Key Words83 Exercises83 Chapter 5Chemical Kinetics85 5ª±1Reaction Rates85 5ª±2Theories of Reaction Rates 87 5ª±3Effect of Concentration on Rate of Reaction89 5ª±4Rate and Temperature92 5ª±5Catalysis94 Key Words95 Exercises96 Chapter 6Chemical Equilibrium98 6ª±1Concept of Equilibrium98 6ª±2Equilibrium Constant98 6ª±3Le Ch¢{telier¬ðs Principle103 Key Words106 Exercises106 Chapter 7Solutions108 7ª±1Ways of Expressing Concentration108 7ª±2Colligative Properties113 Key Words124 Exercises125 Chapter 8Solubility Equilibrium127 8ª±1Saturated Solutions and Solubility127 8ª±2Solubility Equilibria127 8ª±3Factors Affecting Solubility130 8ª±4Predicting Precipitation Reaction132 8ª±5Selective Precipitation134 8ª±6Application of Precipitate on Medicine137 Key Words138 Exercises139 Chapter 9Acidª²Base Equilibria141 9ª±1Acids and Bases141 9ª±2Ion Product of Water143 9ª±3Strength of Weak Acids and Bases144 9ª±4The pH of Weak Acids and Bases146 9ª±5The Commonª²Ion Effect148 9ª±6Buffer Solutions150 Key Words153 Exercises153 Chapter 10An Introduction to Electrochemistry155 10ª±1Oxidationª²Reduction Reactions155 10ª±2Balancing Oxidationª²Reduction Equations158 10ª±3Voltaic Cells161 10ª±4Standard Cell Electromotive Force164 10ª±5Electrochemistry and Thermodynamics171 10ª±6Effect of Concentration on Cell EMF172 10ª±7Reduction Potential Diagrams of Elements(Latimer Diagrams)174 Key Words177 Exercises177 Chapter 11Chemistry of Coordination Compounds180 11ª±1The History of Coordination Chemistry180 11ª±2Formation of Coordination Compound182 11ª±3Nomenclature of Coordination Compounds184 11ª±4Structure and Isomerism 185 11ª±5Coordination Equilibrium in Solution187 11ª±6Valence Bond Theory of Coordination Compounds191 11ª±7The Crystal Field Theory194 11ª±8The Biological Effects of Coordination Compounds199 Key Words200 Exercises201 Chapter 12Nonmetals and Semimetals203 12ª±1General Concepts203 12ª±2Hydrogen203 12ª±3Boron204 12ª±4The Group ¢ôA Elements£¬the Carbon Group Elements205 12ª±5The Group¢õA Elements£¬the Nitrogen Group Elements208 12ª±6The Group ¢öA Elements£¬the Oxygen Group Elements211 12ª±7The Group ¢÷A Elements£¬the Halogens215 12ª±8The Group ¢øA Elements£¬the Noble Gases218 Key Words218 Exercises219 Chapter 13Metals 220 13ª±1The Group IA Elements220 13ª±2The Group ¢òA Elements224 13ª±3The Group ¢óA Elements229 13ª±4A Survey of Transition Metals232 13ª±5Chemistry of Some Transition Metals234 Key Words239 Exercises239 ¢òInorganic Chemical Experiments241 Chapter 1Basic Techniques of Experimental Chemistry242 1ª±1Safety242 1ª±2Recording Results243 1ª±3Weighing243 1ª±4Concerning Liquids244 Chapter 2Typical Chemical Laboratory Apparatus 252 Chapter 3Experiments254 3ª±1Some Elementary Operation254 3ª±2Acidª²Base Titration256 3ª±3Electrolyte Solutions259 3ª±4Preparation of Officinal Sodium Chloride and Its Purity Examination 262 3ª±5Oxidationª²Reduction Reactions267 3ª±6Coordination Compounds271 3ª±7The Halogens275 3ª±8Chromium,Manganese and Iron278 3ª±9Copper,Silver,Zinc and Mercury283 3ª±10Determination of the Ionization Constant of HAc by pH Meter287 3ª±11Preparation of Ammonium Iron(¢ò)Sulfate291 3ª±12Preparation and Content Determination of Zinc Gluconate294 Appendix296 Reference308